Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate
نویسندگان
چکیده
In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octa-hedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N'-bidentate 10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene (TBBT) mol-ecules and two chloride ions. In the crystal, π-π aromatic stacking inter-actions between adjacent TTBT rings are seen, with a centroid-centroid distance of 3.604 (3) Å. An O-H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.
منابع مشابه
Chlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene-κ2 N 4,N 5)copper(I)
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2008